Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/148226
Title: Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates
Authors: Zhou, Steve Jianrong
Huang, Xiaolei
Teng, Shenghan
Chi, Robin Yonggui
Keywords: Science::Chemistry
Issue Date: 2021
Source: Zhou, S. J., Huang, X., Teng, S. & Chi, R. Y. (2021). Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates. Chemical Communications, 57(32), 3933-3936. https://dx.doi.org/10.1039/D1CC00634G
Journal: Chemical Communications
Abstract: Nickel-catalyzed Heck reaction of cycloalkenes delivers unusual conjugated arylated isomers. Nickel(0) catalysts ligated by chelating dialkylphosphines effectively activate not only aryl triflates as electrophiles, but also less reactive aryl mesylates, tosylates and pivalates. The omission of bases allows nickel hydride species to exist long enough to perform in situ olefin isomerization of initial Heck adducts.
URI: https://hdl.handle.net/10356/148226
ISSN: 1364-548X
DOI: 10.1039/D1CC00634G
Rights: © 2021 The Author(s) (Royal Society of Chemistry). All rights reserved. This paper was published in [Chemical Communications and is made available with permission of The Author(s) (Royal Society of Chemistry).
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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