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https://hdl.handle.net/10356/148226| Title: | Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates | Authors: | Zhou, Steve Jianrong Huang, Xiaolei Teng, Shenghan Chi, Robin Yonggui |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Zhou, S. J., Huang, X., Teng, S. & Chi, R. Y. (2021). Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates. Chemical Communications, 57(32), 3933-3936. https://dx.doi.org/10.1039/D1CC00634G | Journal: | Chemical Communications | Abstract: | Nickel-catalyzed Heck reaction of cycloalkenes delivers unusual conjugated arylated isomers. Nickel(0) catalysts ligated by chelating dialkylphosphines effectively activate not only aryl triflates as electrophiles, but also less reactive aryl mesylates, tosylates and pivalates. The omission of bases allows nickel hydride species to exist long enough to perform in situ olefin isomerization of initial Heck adducts. | URI: | https://hdl.handle.net/10356/148226 | ISSN: | 1364-548X | DOI: | 10.1039/D1CC00634G | Rights: | © 2021 The Author(s) (Royal Society of Chemistry). All rights reserved. This paper was published in [Chemical Communications and is made available with permission of The Author(s) (Royal Society of Chemistry). | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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