Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/148227
Title: Carbene-catalyzed selective addition of isothioureas to enals for access to sulphur-containing 5,6-dihyropyrimidin-4-ones
Authors: Maiti, Rakesh
Xu, Jun
Yan, Jia-Lei
Mondal, Bivas
Yang, Xing
Chai, Huifang
Hao, Lin
Jin, Zhichao
Chi, Robin Yonggui
Keywords: Science::Chemistry
Issue Date: 2021
Source: Maiti, R., Xu, J., Yan, J., Mondal, B., Yang, X., Chai, H., Hao, L., Jin, Z. & Chi, R. Y. (2021). Carbene-catalyzed selective addition of isothioureas to enals for access to sulphur-containing 5,6-dihyropyrimidin-4-ones. Organic Chemistry Frontiers, 8(4), 743-747. https://dx.doi.org/10.1039/D0QO01380C
Journal: Organic Chemistry Frontiers
Abstract: A carbene-catalyzed addition reaction between isothioureas and enals under oxidative conditions is reported. The key steps of our reactions involve the formation of two carbon–nitrogen bonds in a highly regio-selective manner. A variety of sulphur-containing 5,6-dihydropyrimidin-4-ones are obtained with high optical purity.
URI: https://hdl.handle.net/10356/148227
ISSN: 2052-4129
DOI: 10.1039/D0QO01380C
Rights: © 2021 Partner Organisations (The Chinese Chemical Society, Shanghai Institute of Organic Chemistry, and Royal Society of Chemistry). All rights reserved. This paper was published in Organic Chemistry Frontiers and is made available with permission of Partner Organisations (The Chinese Chemical Society, Shanghai Institute of Organic Chemistry, and Royal Society of Chemistry).
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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