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https://hdl.handle.net/10356/148227| Title: | Carbene-catalyzed selective addition of isothioureas to enals for access to sulphur-containing 5,6-dihyropyrimidin-4-ones | Authors: | Maiti, Rakesh Xu, Jun Yan, Jia-Lei Mondal, Bivas Yang, Xing Chai, Huifang Hao, Lin Jin, Zhichao Chi, Robin Yonggui |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Maiti, R., Xu, J., Yan, J., Mondal, B., Yang, X., Chai, H., Hao, L., Jin, Z. & Chi, R. Y. (2021). Carbene-catalyzed selective addition of isothioureas to enals for access to sulphur-containing 5,6-dihyropyrimidin-4-ones. Organic Chemistry Frontiers, 8(4), 743-747. https://dx.doi.org/10.1039/D0QO01380C | Journal: | Organic Chemistry Frontiers | Abstract: | A carbene-catalyzed addition reaction between isothioureas and enals under oxidative conditions is reported. The key steps of our reactions involve the formation of two carbon–nitrogen bonds in a highly regio-selective manner. A variety of sulphur-containing 5,6-dihydropyrimidin-4-ones are obtained with high optical purity. | URI: | https://hdl.handle.net/10356/148227 | ISSN: | 2052-4129 | DOI: | 10.1039/D0QO01380C | Rights: | © 2021 Partner Organisations (The Chinese Chemical Society, Shanghai Institute of Organic Chemistry, and Royal Society of Chemistry). All rights reserved. This paper was published in Organic Chemistry Frontiers and is made available with permission of Partner Organisations (The Chinese Chemical Society, Shanghai Institute of Organic Chemistry, and Royal Society of Chemistry). | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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