Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/148229
Title: Carbene-catalyzed N,N-nucleophilic activation of thioureas for access to pyrimidinthione derivatives
Authors: Cao, Liya
Li, Tingting
Chi, Robin Yonggui
Jin, Zhichao
Keywords: Science::Chemistry
Issue Date: 2021
Source: Cao, L., Li, T., Chi, R. Y. & Jin, Z. (2021). Carbene-catalyzed N,N-nucleophilic activation of thioureas for access to pyrimidinthione derivatives. Asian Journal of Organic Chemistry, 10(5), 1090-1093. https://dx.doi.org/10.1002/ajoc.202100113
Journal: Asian Journal of Organic Chemistry
Abstract: An N-heterocyclic carbene-catalyzed [3+3] cycloaddition reaction of acylthioureas with ynals is reported. Both N atoms in the thiourea substrate are activated as nucleophiles and incorporated inside the ring system of the product. Pyrimidinthione derivatives bearing various substituents and substitution patterns are afforded as the products in moderate to good yields.
URI: https://hdl.handle.net/10356/148229
ISSN: 2193-5815
DOI: 10.1002/ajoc.202100113
Rights: This is the peer reviewed version of the following article: Cao, L., Li, T., Chi, R. Y. & Jin, Z. (2021). Carbene-catalyzed N,N-nucleophilic activation of thioureas for access to pyrimidinthione derivatives. Asian Journal of Organic Chemistry, 10(5), 1090-1093. https://dx.doi.org/10.1002/ajoc.202100113, which has been published in final form at https://doi.org/10.1002/ajoc.202100113. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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