Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/149738
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dc.contributor.authorMuhammad Luthfi Ismailen_US
dc.contributor.authorOng, Melissa Xin-Yien_US
dc.contributor.authorSo, Cheuk-Waien_US
dc.date.accessioned2021-07-02T07:48:28Z-
dc.date.available2021-07-02T07:48:28Z-
dc.date.issued2020-
dc.identifier.citationMuhammad Luthfi Ismail, Ong, M. X. & So, C. (2020). A base-stabilized germylenyl silaneditelluroate and 1,3-diaza-2-silaallylgermylene. European Journal of Inorganic Chemistry, 2020(38), 3703-3707. https://dx.doi.org/10.1002/ejic.202000552en_US
dc.identifier.issn1434-1948en_US
dc.identifier.other0000-0003-4816-9801-
dc.identifier.urihttps://hdl.handle.net/10356/149738-
dc.description.abstractThe trapping of a transient base-stabilized germylenylsilylene by elemental tellurium and arylazide is described. The reaction of the potassium 2-imino-5,6-methylenedioxylphenylgermylidenide [L GeK] (L = 2-imino-5,6-methylenedioxylphenyl) with the amidinato chlorosilylene [L SiCl] {L = PhC(NtBu) } in THF at –78 °C afforded the transient base-stabilized germylenylsilylene [L SiGeL ] (3). It was unstable in solution, but can be trapped by reacting with elemental tellurium and 2,6-diisopropylphenylazide ArN (Ar = 2,6-iPr C H ) to form the first base-stabilized germylenyl silaneditelluroate [L GeTeSi(=Te)L ] (4) and 1,3-diaza-2-silaallylgermylene complex [{L Si(NAr) }GeL ] (5), respectively. In these reactions, elemental tellurium and ArN insert into the :Si–Ge: bond in 3, followed by oxidation of the Si center with the substrates to form compounds 4 and 5, respectively. Compounds 4 and 5 were characterized by X-ray crystallography. iminophenyl iminophenyl amidinate amidinate 2 amidinate iminophenyl 3 2 6 3 iminophenyl amidinate amidinate 2 iminophenyl 3en_US
dc.language.isoenen_US
dc.relationNRF2018-NRF-ANR026 Si-POPen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.rightsThis is the peer reviewed version of the following article: Muhammad Luthfi Ismail, Ong, M. X. & So, C. (2020). A base-stabilized germylenyl silaneditelluroate and 1,3-diaza-2-silaallylgermylene. European Journal of Inorganic Chemistry, 2020(38), 3703-3707, which has been published in final form at https://doi.org/10.1002/ejic.202000552. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectScience::Chemistry::Inorganic chemistryen_US
dc.titleA base-stabilized germylenyl silaneditelluroate and 1,3-diaza-2-silaallylgermyleneen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1002/ejic.202000552-
dc.description.versionAccepted versionen_US
dc.identifier.scopus2-s2.0-85090121793-
dc.identifier.issue38en_US
dc.identifier.volume2020en_US
dc.identifier.spage3703en_US
dc.identifier.epage3707en_US
dc.subject.keywordsSilyleneen_US
dc.subject.keywordsGermyleneen_US
dc.description.acknowledgementThis work is supported by the National Research Foundation Singapore, NRF-ANR (NRF2018-NRF-ANR026 Si-POP).en_US
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