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|Title:||Tuning the reduction potential of quinones by controlling the effects of hydrogen bonding, protonation and proton-coupled electron transfer reactions||Authors:||Shi, Raymond Rong Sheng
Tessensohn, Malcolm Eugene
Lauw, Sherman Jun Liang
Foo, Nicolette A. B. Y.
Webster, Richard David
|Keywords:||Science::Chemistry||Issue Date:||2019||Source:||Shi, R. R. S., Tessensohn, M. E., Lauw, S. J. L., Foo, N. A. B. Y. & Webster, R. D. (2019). Tuning the reduction potential of quinones by controlling the effects of hydrogen bonding, protonation and proton-coupled electron transfer reactions. Chemical Communications, 55(16), 2277-2280. https://dx.doi.org/10.1039/c8cc09188a||Project:||RG109/15||Journal:||Chemical Communications||Abstract:||An all-organic cell comprising 2,3-dimethyl-1,4-napthoquinone and pyrano[3,2-f]chromene as electroactive elements exhibited a good combination of large cell voltage and stability of the reduced quinone upon the addition of diethyl malonate (a weak organic acid), as compared to the addition of trifluoroethanol (which led to a high cell potential but low stability via strong hydrogen bonding interactions) and the addition of trifluoroacetic acid (which led to a lower cell potential but high stability through proton transfer).||URI:||https://hdl.handle.net/10356/150310||ISSN:||1359-7345||DOI:||10.1039/c8cc09188a||Rights:||© 2019 The Royal Society of Chemistry. All rights reserved,||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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