Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/151240
Title: Discharge and densification in the spark plasma sintering of quasicrystal particles
Authors: Li, Ruitao
Liu, Qing
Tian, Lihui
Wang, Yun
Khor, Khiam Aik
Zhang, Di
Dong, Zhili
Keywords: Engineering::Materials
Issue Date: 2019
Source: Li, R., Liu, Q., Tian, L., Wang, Y., Khor, K. A., Zhang, D. & Dong, Z. (2019). Discharge and densification in the spark plasma sintering of quasicrystal particles. Journal of Materials Science, 54(11), 8727-8742. https://dx.doi.org/10.1007/s10853-019-03489-6
Project: RG93/16
Journal: Journal of Materials Science
Abstract: To investigate the micromechanisms involved in the spark plasma sintering of quasicrystals, thin foils were extracted from samples by focused ion beam at the interrupted states and analysed by transmission electron microscopy for the first time. Material jets are present between adjacent particles, indicating the occurrence of discharge/plasma. Surficial material melts first due to discharge and the liquid sputters as a result of the action of electric field, forming material jets. Discharge occurs in all the cavities with the largest gap size of 60 nm. Gap size is a deciding factor for the formation of material jets: Thick jets are only formed in narrow gaps (< 20 nm), while very thin jets or even no jets are present in wide gaps (> 20 nm). A low voltage (< 0.016 V) is needed to trigger the discharge, and it is inferred that quantum tunnelling and thermal excitation promote the formation of discharge within nanopores at relatively high temperatures. Discharge contributes very little to the densification, while the plastic deformation, meditated by a unique type of defect—metadislocations, is the dominant mechanism for it. The phase transformation of icosahedral Al–Cu–Fe–Cr to its crystalline approximants is accompanied by the formation of planar faults.
URI: https://hdl.handle.net/10356/151240
ISSN: 0022-2461
DOI: 10.1007/s10853-019-03489-6
Rights: © 2019 Springer Science+Business Media, LLC, part of Springer Nature. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MAE Journal Articles
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