Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/151949
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dc.contributor.authorZhang, Pengen_US
dc.contributor.authorWang, Siboen_US
dc.contributor.authorGuan, Bu Yuanen_US
dc.contributor.authorLou, David Xiong Wenen_US
dc.date.accessioned2021-07-19T10:44:31Z-
dc.date.available2021-07-19T10:44:31Z-
dc.date.issued2019-
dc.identifier.citationZhang, P., Wang, S., Guan, B. Y. & Lou, D. X. W. (2019). Fabrication of CdS hierarchical multi-cavity hollow particles for efficient visible light CO₂ reduction. Energy & Environmental Science, 12(1), 164-168. https://dx.doi.org/10.1039/C8EE02538Jen_US
dc.identifier.issn1754-5692en_US
dc.identifier.urihttps://hdl.handle.net/10356/151949-
dc.description.abstractDesigning advanced structures for semiconductor photocatalysts is an effective approach to enhance their performance. However, it is not easy to fabricate functional photocatalytic materials with complex nano-architectures. Here we have developed a sequential solution growth, sulfidation and cation-exchange strategy to fabricate CdS hierarchical multi-cavity hollow particles (HMCHPs). This strategy starts with the growth of Zn-based zeolitic imidazolate framework (ZIF-8) onto cobalt glycerate (Co-G) solid spheres. Sulfidation of the obtained Co-G@ZIF-8 composite particles leads to the formation of CoSₓ@ZnS HMCHPs, which are converted into CdS HMCHPs via a cation-exchange reaction. Owing to the favourable properties of the well-defined hierarchical hollow structure, the CdS HMCHPs exhibit enhanced activity for photocatalytic CO₂ reduction compared with other CdS photocatalysts with solid and common hollow structures. The performance of CdS HMCHPs can be further promoted by loading of Au to reach a CO generation rate of 3758 μmol h⁻¹ g⁻¹ under visible light irradiation.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.language.isoenen_US
dc.relationMOE2017-T2-2-003(S)en_US
dc.relationM4020386en_US
dc.relation.ispartofEnergy & Environmental Scienceen_US
dc.rights© 2019 The Royal Society of Chemistry. All rights reserved.en_US
dc.subjectEngineering::Chemical engineeringen_US
dc.titleFabrication of CdS hierarchical multi-cavity hollow particles for efficient visible light CO₂ reductionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.identifier.doi10.1039/C8EE02538J-
dc.identifier.issue1en_US
dc.identifier.volume12en_US
dc.identifier.spage164en_US
dc.identifier.epage168en_US
dc.subject.keywordsPhotocatalytic Reductionen_US
dc.subject.keywordsCarbon Nitrideen_US
dc.description.acknowledgementX. W. Lou is grateful to the Ministry of Education of Singapore for the funding support through AcRF Tier 2 grant (MOE2017-T2-2-003(S); M4020386).en_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
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