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|Title:||Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange||Authors:||Chen, Xiao-Hui
|Keywords:||Engineering::Chemical engineering||Issue Date:||2019||Source:||Chen, X., Wei, Q., Hong, J., Xu, R. & Zhou, T. (2019). Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange. Rare Metals, 38(5), 413-419. https://dx.doi.org/10.1007/s12598-019-01259-6||Journal:||Rare Metals||Abstract:||Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of well-defined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework (MOF) was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands. This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2 reduction.||URI:||https://hdl.handle.net/10356/152191||ISSN:||1001-0521||DOI:||10.1007/s12598-019-01259-6||Rights:||© 2019 The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany, part of Springer Nature. All rights reserved.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SCBE Journal Articles|
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