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Title: Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange
Authors: Chen, Xiao-Hui
Wei, Qin
Hong, Jin-Dui
Xu, Rong
Zhou, Tian-Hua
Keywords: Engineering::Chemical engineering
Issue Date: 2019
Source: Chen, X., Wei, Q., Hong, J., Xu, R. & Zhou, T. (2019). Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange. Rare Metals, 38(5), 413-419.
Journal: Rare Metals
Abstract: Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of well-defined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework (MOF) was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands. This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2 reduction.
ISSN: 1001-0521
DOI: 10.1007/s12598-019-01259-6
Rights: © 2019 The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany, part of Springer Nature. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SCBE Journal Articles

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