Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/152191
Title: | Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange | Authors: | Chen, Xiao-Hui Wei, Qin Hong, Jin-Dui Xu, Rong Zhou, Tian-Hua |
Keywords: | Engineering::Chemical engineering | Issue Date: | 2019 | Source: | Chen, X., Wei, Q., Hong, J., Xu, R. & Zhou, T. (2019). Bifunctional metal–organic frameworks toward photocatalytic CO₂ reduction by post-synthetic ligand exchange. Rare Metals, 38(5), 413-419. https://dx.doi.org/10.1007/s12598-019-01259-6 | Journal: | Rare Metals | Abstract: | Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of well-defined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework (MOF) was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands. This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2 reduction. | URI: | https://hdl.handle.net/10356/152191 | ISSN: | 1001-0521 | DOI: | 10.1007/s12598-019-01259-6 | Schools: | School of Chemical and Biomedical Engineering | Rights: | © 2019 The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany, part of Springer Nature. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SCBE Journal Articles |
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