Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154141
Title: Diastereoselective hydroalkylation of aryl alkenes enabled by remote hydride transfer
Authors: Gandamana, Dhika Aditya
Gagosz, Fabien
Chiba, Shunsuke
Keywords: Science::Chemistry
Issue Date: 2020
Source: Gandamana, D. A., Gagosz, F. & Chiba, S. (2020). Diastereoselective hydroalkylation of aryl alkenes enabled by remote hydride transfer. Tetrahedron, 76(51), 131272-. https://dx.doi.org/10.1016/j.tet.2020.131272
Project: RG2/18
Journal: Tetrahedron
Abstract: Leveraging of 1,5-hydride shift enabled diastereoselective hydroalkylation of aryl alkenes, allowing for construction of consecutive vicinal stereogenic centers in a single process. The transformation is triggered by electrophilic alkylation of aryl alkenes with in-situ generated carbocations, that is followed by diastereoselective 1,5-hydride shift to the resulting benzylic carbocation through a rigid 6-membered ring chair-like transition state.
URI: https://hdl.handle.net/10356/154141
ISSN: 0040-4020
DOI: 10.1016/j.tet.2020.131272
Rights: © 2020 Elsevier Ltd. All rights reserved. This paper was published in Tetrahedron and is made available with permission of Elsevier Ltd.
Fulltext Permission: embargo_20221225
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

Files in This Item:
File Description SizeFormat 
manuscript_Chiba_rev_deposit.pdf
  Until 2022-12-25
7.57 MBAdobe PDFUnder embargo until Dec 25, 2022

SCOPUSTM   
Citations 50

1
Updated on Jan 8, 2022

PublonsTM
Citations 50

1
Updated on Jan 9, 2022

Page view(s)

17
Updated on Jan 24, 2022

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.