Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154284
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dc.contributor.authorBellido-Aguilar, Daniel Angelen_US
dc.contributor.authorZheng, Shunlien_US
dc.contributor.authorHuang, Yinjuanen_US
dc.contributor.authorSun, Yeen_US
dc.contributor.authorZeng, Xiantingen_US
dc.contributor.authorZhang, Qichunen_US
dc.contributor.authorChen, Zhongen_US
dc.date.accessioned2021-12-16T08:16:17Z-
dc.date.available2021-12-16T08:16:17Z-
dc.date.issued2020-
dc.identifier.citationBellido-Aguilar, D. A., Zheng, S., Huang, Y., Sun, Y., Zeng, X., Zhang, Q. & Chen, Z. (2020). Hydrophobization of fully bio-based epoxy polymers using water as solvent : effect of additives. European Polymer Journal, 140, 110043-. https://dx.doi.org/10.1016/j.eurpolymj.2020.110043en_US
dc.identifier.issn0014-3057en_US
dc.identifier.urihttps://hdl.handle.net/10356/154284-
dc.description.abstractCurrent epoxy industry still has a strong dependency on fossil-derived precursors as demonstrated in the use of bisphenol A-based resins. To improve the sustainability of the epoxy industry, bio-based chemicals have been explored for the synthesis of environmentally-friendly epoxy polymers. This paper reports the hydrophobization of fully bio-based epoxy coatings using only water as solvent. Three bio-based additives (hexanoic acid, resveratrol, and a cardanol-based epoxy resin) were studied aiming to enhance the hydrophobicity of the coatings. The curing reaction mechanisms have been extensively explored. The modified coatings showed better hydrophobicity, however, they tend to possess a lower crosslink density because these additives have, to some extent, disrupted the polymer network formation. The anticorrosion performance of the bio-based coatings was also evaluated and discussed based on the reported hydrophobicity and crosslink density. This study lays a foundation towards fully bio-based, environmentally-friendly polymers for hydrophobic applications in the future.en_US
dc.description.sponsorshipAgency for Science, Technology and Research (A*STAR)en_US
dc.language.isoenen_US
dc.relationSERC 1528000048en_US
dc.relation.ispartofEuropean Polymer Journalen_US
dc.rights© 2020 Elsevier Ltd. All rights reserved.en_US
dc.subjectEngineering::Materialsen_US
dc.titleHydrophobization of fully bio-based epoxy polymers using water as solvent : effect of additivesen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1016/j.eurpolymj.2020.110043-
dc.identifier.scopus2-s2.0-85091949920-
dc.identifier.volume140en_US
dc.identifier.spage110043en_US
dc.subject.keywordsBio-Based Polymersen_US
dc.subject.keywordsHexanoic Aciden_US
dc.description.acknowledgementWe would like to express our gratitude to the Agency for Science, Technology and Research (A*STAR) of Singapore for the funds (SERC 1528000048) provided in this research.en_US
item.fulltextNo Fulltext-
item.grantfulltextnone-
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