Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154502
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dc.contributor.authorKatona, Dáviden_US
dc.contributor.authorLu, Yunpengen_US
dc.contributor.authorLi, Yongxinen_US
dc.contributor.authorPullarkat, Sumod A.en_US
dc.contributor.authorLeung, Pak-Hingen_US
dc.date.accessioned2021-12-23T08:11:19Z-
dc.date.available2021-12-23T08:11:19Z-
dc.date.issued2020-
dc.identifier.citationKatona, D., Lu, Y., Li, Y., Pullarkat, S. A. & Leung, P. (2020). Catalytic approach toward chiral P,N-chelate complexes utilizing the asymmetric hydrophosphination protocol. Inorganic Chemistry, 59(6), 3874-3886-3886. https://dx.doi.org/10.1021/acs.inorgchem.9b03549en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttps://hdl.handle.net/10356/154502-
dc.description.abstractA synthetic procedure for obtaining a chiral P,N ligand was developed by exploiting the versatility of the asymmetric hydrophosphination protocol catalyzed by a phosphapalladacycle complex. The addition of the synthesized ligand to various metal sources led to the generation of chiral and enantioenriched chelate complexes, which can be useful prototypes for catalyst design in the future. The resulting coordination compounds were comprehensively characterized by solid-state (X-ray crystallography) and solution-based (one- and two-dimensional NMR spectroscopy) techniques and natural bond orbital (density functional theory) analysis to determine their structural and key electronic features.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relationM4080454en_US
dc.relation2017-T1-001-175-02en_US
dc.relation.ispartofInorganic Chemistryen_US
dc.rights© 2020 American Chemical Society. All rights reserveden_US
dc.subjectScience::Chemistryen_US
dc.titleCatalytic approach toward chiral P,N-chelate complexes utilizing the asymmetric hydrophosphination protocolen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.inorgchem.9b03549-
dc.identifier.pmid32090541-
dc.identifier.scopus2-s2.0-85080128605-
dc.identifier.issue6en_US
dc.identifier.volume59en_US
dc.identifier.spage3874-3886en_US
dc.identifier.epage3886en_US
dc.subject.keywordsRhodium Complexesen_US
dc.subject.keywordsPalladium Catalystsen_US
dc.description.acknowledgementWe thank Nanyang Technological University for enabling and supporting our research [Grants M4080454 (NTU) and 2017- T1-001-175-02 (MOE)] and for a SINGA scholarship supporting D.K. in his studies.en_US
item.grantfulltextnone-
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