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Title: Catalytic approach toward chiral P,N-chelate complexes utilizing the asymmetric hydrophosphination protocol
Authors: Katona, Dávid
Lu, Yunpeng
Li, Yongxin
Pullarkat, Sumod A.
Leung, Pak-Hing
Keywords: Science::Chemistry
Issue Date: 2020
Source: Katona, D., Lu, Y., Li, Y., Pullarkat, S. A. & Leung, P. (2020). Catalytic approach toward chiral P,N-chelate complexes utilizing the asymmetric hydrophosphination protocol. Inorganic Chemistry, 59(6), 3874-3886-3886.
Project: M4080454
Journal: Inorganic Chemistry
Abstract: A synthetic procedure for obtaining a chiral P,N ligand was developed by exploiting the versatility of the asymmetric hydrophosphination protocol catalyzed by a phosphapalladacycle complex. The addition of the synthesized ligand to various metal sources led to the generation of chiral and enantioenriched chelate complexes, which can be useful prototypes for catalyst design in the future. The resulting coordination compounds were comprehensively characterized by solid-state (X-ray crystallography) and solution-based (one- and two-dimensional NMR spectroscopy) techniques and natural bond orbital (density functional theory) analysis to determine their structural and key electronic features.
ISSN: 0020-1669
DOI: 10.1021/acs.inorgchem.9b03549
Rights: © 2020 American Chemical Society. All rights reserved
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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