Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154504
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dc.contributor.authorBarik, Chandan Kren_US
dc.contributor.authorGanguly, Rakeshen_US
dc.contributor.authorGarcia, Felipeen_US
dc.contributor.authorLeong, Weng Keeen_US
dc.date.accessioned2021-12-23T08:18:16Z-
dc.date.available2021-12-23T08:18:16Z-
dc.date.issued2020-
dc.identifier.citationBarik, C. K., Ganguly, R., Garcia, F. & Leong, W. K. (2020). Encapsulating ruthenium in silica using a single source precursor : differing outcomes for a cycloaddition reaction. Inorganica Chimica Acta, 512, 119833-. https://dx.doi.org/10.1016/j.ica.2020.119833en_US
dc.identifier.issn0020-1693en_US
dc.identifier.urihttps://hdl.handle.net/10356/154504-
dc.description.abstractThe complex [Ru2(CO)4(µ-O2CCH2OSi(OEt)3)2(PPh3)2] was used as a single-source precursor to prepare silica-encapsulated ruthenium via hydrolysis followed by calcination. While the silica-encapsulated ruthenium catalyst and the molecular precursor both catalysed the [2 + 1] cycloaddition reaction between alkenes and ethyl diazoacetate to form cyclopropanes, the intermediate hydrolysis product partially directed the reaction towards [2 + 3] cycloaddition to form cyclic five-membered pyrazolines.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relationM4012079en_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.rights© 2020 Elsevier B.V. All rights reserved.en_US
dc.subjectScience::Chemistryen_US
dc.titleEncapsulating ruthenium in silica using a single source precursor : differing outcomes for a cycloaddition reactionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.departmentDivision of Chemistry & Biological Chemistryen_US
dc.identifier.doi10.1016/j.ica.2020.119833-
dc.identifier.scopus2-s2.0-85087526590-
dc.identifier.volume512en_US
dc.identifier.spage119833en_US
dc.subject.keywordsSingle Source Precursoren_US
dc.subject.keywordsRuthenium Complexesen_US
dc.description.acknowledgementThis work was supported by Nanyang Technological University and the Ministry of Education (Research Grant No. M4012079)en_US
item.fulltextNo Fulltext-
item.grantfulltextnone-
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