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https://hdl.handle.net/10356/154827| Title: | Hydroalkylation of styrenes with benzylamines by potassium hydride | Authors: | Pang, Jia Hao Wang, Bin Watanabe, Kohei Takita, Ryo Chiba, Shunsuke |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Pang, J. H., Wang, B., Watanabe, K., Takita, R. & Chiba, S. (2021). Hydroalkylation of styrenes with benzylamines by potassium hydride. Helvetica Chimica Acta, 104(10), e2100120-. https://dx.doi.org/10.1002/hlca.202100120 | Project: | MOE2019-T2-1-089 | Journal: | Helvetica Chimica Acta | Abstract: | A method for the synthesis of 1,3-diarylpropylamines through hydroalkylation of styrenes with benzylamines by potassium hydride has been developed. The protocol is initiated by solvothermal treatment of benzylamines with KH at 100 °C to generate deprotonated anionic species, which undergo selective C-alkylation with arylalkenes at 0 °C to ambient temperature to afford 1,3-diarylpropylamines as the major product. | URI: | https://hdl.handle.net/10356/154827 | ISSN: | 1522-2675 | DOI: | 10.1002/hlca.202100120 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2021 Wiley-VHCA AG. All rights reserved. This paper was published in Helvetica Chimica Acta and is made available with permission of Wiley-VHCA AG. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| manuscript_Chiba_rev_deposit.pdf | 472.37 kB | Adobe PDF |  View/Open |
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