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https://hdl.handle.net/10356/154832| Title: | Hydromagnesiation of 1,3-enynes by magnesium hydride for synthesis of tri- and tetra-substituted allenes | Authors: | Wang, Bin Li, Yihang Pang, Jia Hao Watanabe, Kohei Takita, Ryo Chiba, Shunsuke |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Wang, B., Li, Y., Pang, J. H., Watanabe, K., Takita, R. & Chiba, S. (2021). Hydromagnesiation of 1,3-enynes by magnesium hydride for synthesis of tri- and tetra-substituted allenes. Angewandte Chemie International Edition, 60(1), 217-221. https://dx.doi.org/10.1002/anie.202012027 | Project: | MOE2019-T2-1-089 | Journal: | Angewandte Chemie International Edition | Abstract: | A protocol for regio-controlled hydromagnesiation of 1,3-enynes was developed using magnesium hydride that is generated in situ by solvothermal treatment of sodium hydride (NaH) and magnesium iodide (MgI2 ) in THF. The resulting allenylmagnesium species could be converted into tri- and tetra-substituted allenes by subsequent treatment with various carbon- and silicon-based electrophiles with the aid of CuCN as a catalyst. | URI: | https://hdl.handle.net/10356/154832 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.202012027 | Schools: | School of Physical and Mathematical Sciences | Rights: | This is the peer reviewed version of the following article: Wang, B., Li, Y., Pang, J. H., Watanabe, K., Takita, R. & Chiba, S. (2021). Hydromagnesiation of 1,3-enynes by magnesium hydride for synthesis of tri- and tetra-substituted allenes. Angewandte Chemie International Edition, 60(1), 217-221, which has been published in final form at https://doi.org/10.1002/anie.202012027. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| manuscript_Chiba_rev_deposit.pdf | 530.22 kB | Adobe PDF |  View/Open |
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