Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154849
Title: Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates
Authors: Hayashi, Hirohito
Kaga, Atsushi
Wang, Bin
Gagosz, Fabien
Chiba, Shunsuke
Keywords: Science::Chemistry
Issue Date: 2018
Source: Hayashi, H., Kaga, A., Wang, B., Gagosz, F. & Chiba, S. (2018). Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates. Chemical Communications, 54(54), 7535-7538. https://dx.doi.org/10.1039/c8cc02971g
Project: RG2/15
Journal: Chemical Communications
Abstract: A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.
URI: https://hdl.handle.net/10356/154849
ISSN: 1359-7345
DOI: 10.1039/c8cc02971g
Rights: © 2018 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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