Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/154849
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dc.contributor.authorHayashi, Hirohitoen_US
dc.contributor.authorKaga, Atsushien_US
dc.contributor.authorWang, Binen_US
dc.contributor.authorGagosz, Fabienen_US
dc.contributor.authorChiba, Shunsukeen_US
dc.date.accessioned2022-01-14T08:27:50Z-
dc.date.available2022-01-14T08:27:50Z-
dc.date.issued2018-
dc.identifier.citationHayashi, H., Kaga, A., Wang, B., Gagosz, F. & Chiba, S. (2018). Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates. Chemical Communications, 54(54), 7535-7538. https://dx.doi.org/10.1039/c8cc02971gen_US
dc.identifier.issn1359-7345en_US
dc.identifier.urihttps://hdl.handle.net/10356/154849-
dc.description.abstractA new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relationRG2/15en_US
dc.relation.ispartofChemical Communicationsen_US
dc.rights© 2018 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.en_US
dc.subjectScience::Chemistryen_US
dc.titleUse of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthatesen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1039/c8cc02971g-
dc.description.versionAccepted versionen_US
dc.identifier.pmid29926014-
dc.identifier.scopus2-s2.0-85049515374-
dc.identifier.issue54en_US
dc.identifier.volume54en_US
dc.identifier.spage7535en_US
dc.identifier.epage7538en_US
dc.subject.keywordsAlkene Derivativeen_US
dc.subject.keywordsBenzyl Derivativeen_US
dc.description.acknowledgementThis work was supported by funding from Nanyang Technological University (for S. C.), the Singapore Ministry of Education (Academic Research Fund Tier 1: RG2/15 for S. C.) and the Natural Sciences and Engineering Research Council (for F. G.). F. G. and S. C. are grateful to the PHC Merlion grant (Project 5.02.15) for the support of this collaboration project.en_US
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