Please use this identifier to cite or link to this item:
|Title:||Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates||Authors:||Hayashi, Hirohito
|Keywords:||Science::Chemistry||Issue Date:||2018||Source:||Hayashi, H., Kaga, A., Wang, B., Gagosz, F. & Chiba, S. (2018). Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates. Chemical Communications, 54(54), 7535-7538. https://dx.doi.org/10.1039/c8cc02971g||Project:||RG2/15||Journal:||Chemical Communications||Abstract:||A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the remote radical hydrogen atom transfer event during the process.||URI:||https://hdl.handle.net/10356/154849||ISSN:||1359-7345||DOI:||10.1039/c8cc02971g||Rights:||© 2018 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SPMS Journal Articles|
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.