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https://hdl.handle.net/10356/154854| Title: | Nucleophilic amination of methoxy arenes promoted by a sodium hydride/iodide composite | Authors: | Kaga, Atsushi Hayashi, Hirohito Hakamata, Hiroyuki Oi, Miku Uchiyama, Masanobu Takita, Ryo Chiba, Shunsuke |
Keywords: | Science::Chemistry | Issue Date: | 2017 | Source: | Kaga, A., Hayashi, H., Hakamata, H., Oi, M., Uchiyama, M., Takita, R. & Chiba, S. (2017). Nucleophilic amination of methoxy arenes promoted by a sodium hydride/iodide composite. Angewandte Chemie International Edition, 56(39), 11807-11811. https://dx.doi.org/10.1002/anie.201705916 | Project: | RG2/15 | Journal: | Angewandte Chemie International Edition | Abstract: | A method for the nucleophilic amination of methoxy arenes was established by using sodium hydride (NaH) in the presence of lithium iodide (LiI). This method offers an efficient route to benzannulated nitrogen heterocycles. Mechanistic studies showed that the reaction proceeds through an unusual concerted nucleophilic aromatic substitution. | URI: | https://hdl.handle.net/10356/154854 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.201705916 | Schools: | School of Physical and Mathematical Sciences | Rights: | This is the peer reviewed version of the following article: Kaga, A., Hayashi, H., Hakamata, H., Oi, M., Uchiyama, M., Takita, R. & Chiba, S. (2017). Nucleophilic amination of methoxy arenes promoted by a sodium hydride/iodide composite. Angewandte Chemie International Edition, 56(39), 11807-11811, which has been published in final form at https://doi.org/10.1002/anie.201705916. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Manuscript_Chiba_rev_deposit.pdf | 1.22 MB | Adobe PDF |  View/Open |
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