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Title: Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles
Authors: Peng, Xingao
Kaga, Atsushi
Hirao, Hajime
Chiba, Shunsuke
Keywords: Science::Chemistry
Issue Date: 2016
Source: Peng, X., Kaga, A., Hirao, H. & Chiba, S. (2016). Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles. Organic Chemistry Frontiers, 3(5), 609-613.
Project: MOE2012-T2-1-014
Journal: Organic Chemistry Frontiers
Abstract: The t-BuOK-mediated reactions of γ,δ-alkenyl N-arylhydrazones enabled intramolecular hydroamination with the outer nitrogen, affording tetrahydropyridazine derivatives. DFT calculations demonstrated a clear distinction in the chemical reactivity between hydrazones and analogous oximes in inorganic base-mediated hydroamination.
ISSN: 2052-4129
DOI: 10.1039/c6qo00053c
Rights: © 2016 The Partner Organisations. All rights reserved. This paper was published by Royal Society of Chemistry in Organic Chemistry Frontiers and is made available with permission of The Partner Organisations.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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