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https://hdl.handle.net/10356/154865| Title: | Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles | Authors: | Peng, Xingao Kaga, Atsushi Hirao, Hajime Chiba, Shunsuke |
Keywords: | Science::Chemistry | Issue Date: | 2016 | Source: | Peng, X., Kaga, A., Hirao, H. & Chiba, S. (2016). Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles. Organic Chemistry Frontiers, 3(5), 609-613. https://dx.doi.org/10.1039/c6qo00053c | Project: | MOE2012-T2-1-014 | Journal: | Organic Chemistry Frontiers | Abstract: | The t-BuOK-mediated reactions of γ,δ-alkenyl N-arylhydrazones enabled intramolecular hydroamination with the outer nitrogen, affording tetrahydropyridazine derivatives. DFT calculations demonstrated a clear distinction in the chemical reactivity between hydrazones and analogous oximes in inorganic base-mediated hydroamination. | URI: | https://hdl.handle.net/10356/154865 | ISSN: | 2052-4129 | DOI: | 10.1039/c6qo00053c | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2016 The Partner Organisations. All rights reserved. This paper was published by Royal Society of Chemistry in Organic Chemistry Frontiers and is made available with permission of The Partner Organisations. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| OCF_Chiba_rev_2_deposit.pdf | 2.2 MB | Adobe PDF |  View/Open |
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