Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/155069
Title: | Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction | Authors: | Zhu, Daoyong Xu, Wenqiang Pu, Maoping Wu, Yun-Dong Chi, Robin Yonggui Zhou, Steve Jianrong |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Zhu, D., Xu, W., Pu, M., Wu, Y., Chi, R. Y. & Zhou, S. J. (2021). Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction. Organic Letters, 23(18), 7064-7068. https://dx.doi.org/10.1021/acs.orglett.1c02457 | Journal: | Organic Letters | Abstract: | Palladium catalyzes a domino Heck arylation and alkylation of nonconjugated cyclodienes to produce trans isomers of disubstituted cyclohexenes in exceptionally high enantiomeric ratios, reaching 100:1 to 200:1 in many cases. Importantly, the interactions of the two CF bonds of Josiphos and the sodium ion of malonates facilitates stereoselective allylic attack through DFT calculations and experiments. This is a new type of attractive noncovalent interactions found in organometallic catalysis. | URI: | https://hdl.handle.net/10356/155069 | ISSN: | 1523-7060 | DOI: | 10.1021/acs.orglett.1c02457 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2021 American Chemical Society. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
SCOPUSTM
Citations
50
6
Updated on Mar 21, 2024
Web of ScienceTM
Citations
50
2
Updated on Oct 31, 2023
Page view(s)
106
Updated on Mar 28, 2024
Google ScholarTM
Check
Altmetric
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.