Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/155121
Title: Engineering channels of metal-organic frameworks to enhance catalytic selectivity
Authors: Liu, Ye
Shen, Yu
Zhang, Weina
Weng, Jiena
Zhao, Meiting
Zhu, Tingshun
Chi, Robin Yonggui
Yang, Yanhui
Zhang, Hua
Huo, Fengwei
Keywords: Science::Chemistry
Issue Date: 2019
Source: Liu, Y., Shen, Y., Zhang, W., Weng, J., Zhao, M., Zhu, T., Chi, R. Y., Yang, Y., Zhang, H. & Huo, F. (2019). Engineering channels of metal-organic frameworks to enhance catalytic selectivity. Chemical Communications, 55(78), 11770-11773. https://dx.doi.org/10.1039/c9cc06061h
Project: MOE2015-T2-2-057
MOE2016-T2-2- 103
MOE2017-T2-1-162
2016-T1-002-051
2017-T1-001-150
2017-T1-002-119
M4081296.070.500000
Journal: Chemical Communications 
Abstract: This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.
URI: https://hdl.handle.net/10356/155121
ISSN: 1359-7345
DOI: 10.1039/c9cc06061h
Rights: © 2019 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles
SPMS Journal Articles

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