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|Title:||Fragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anion||Authors:||Koshino, Kota
|Keywords:||Science::Chemistry||Issue Date:||2020||Source:||Koshino, K. & Kinjo, R. (2020). Fragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anion. Organometallics, 39(23), 4183-4186. https://dx.doi.org/10.1021/acs.organomet.0c00444||Project:||MOE2018-T2-2- 048(S)||Journal:||Organometallics||Abstract:||The stable cyclic (alkyl)(amino)alumanyl anion (CAAAl) 3 reacts with white phosphorus (P4) under ambient conditions, in which P4is fragmented into a P1unit to afford the bis(alumanyl)phosphide 2, demonstrating the direct formation of a P anion from an Al anion. Structural and electronic features of the latter were fully characterized by standard spectroscopic means, X-ray diffraction analysis, and computational studies, which revealed that 2 bears highly polarized Al (δ+) and P (δ-) and relatively short Al-P bonds, indicative of the σ-donating and π-accepting nature of CAAAl groups.||URI:||https://hdl.handle.net/10356/155199||ISSN:||0276-7333||DOI:||10.1021/acs.organomet.0c00444||Rights:||© 2020 American Chemical Society. All rights reserved.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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