Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/155199
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dc.contributor.authorKoshino, Kotaen_US
dc.contributor.authorKinjo, Reien_US
dc.date.accessioned2022-02-15T05:12:29Z-
dc.date.available2022-02-15T05:12:29Z-
dc.date.issued2020-
dc.identifier.citationKoshino, K. & Kinjo, R. (2020). Fragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anion. Organometallics, 39(23), 4183-4186. https://dx.doi.org/10.1021/acs.organomet.0c00444en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttps://hdl.handle.net/10356/155199-
dc.description.abstractThe stable cyclic (alkyl)(amino)alumanyl anion (CAAAl) 3 reacts with white phosphorus (P4) under ambient conditions, in which P4is fragmented into a P1unit to afford the bis(alumanyl)phosphide 2, demonstrating the direct formation of a P anion from an Al anion. Structural and electronic features of the latter were fully characterized by standard spectroscopic means, X-ray diffraction analysis, and computational studies, which revealed that 2 bears highly polarized Al (δ+) and P (δ-) and relatively short Al-P bonds, indicative of the σ-donating and π-accepting nature of CAAAl groups.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relationMOE2018-T2-2- 048(S)en_US
dc.relation.ispartofOrganometallicsen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.0c00444.en_US
dc.subjectScience::Chemistryen_US
dc.titleFragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.organomet.0c00444-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.scopus2-s2.0-85090481984-
dc.identifier.issue23en_US
dc.identifier.volume39en_US
dc.identifier.spage4183en_US
dc.identifier.epage4186en_US
dc.subject.keywordsAluminumen_US
dc.subject.keywordsPhosphorusen_US
dc.description.acknowledgementWe are grateful to Nanyang Technological University (NTU) and the Singapore Ministry of Education (MOE2018-T2-2- 048(S)) for financial support.en_US
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