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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Xie, Peizhong | en_US |
dc.contributor.author | Sun, Zuolian | en_US |
dc.contributor.author | Li, Shuangshuang | en_US |
dc.contributor.author | Cai, Xinying | en_US |
dc.contributor.author | Qiu, Ju | en_US |
dc.contributor.author | Fu, Weishan | en_US |
dc.contributor.author | Gao, Cuiqing | en_US |
dc.contributor.author | Wu, Shisheng | en_US |
dc.contributor.author | Yang, Xiaobo | en_US |
dc.contributor.author | Loh, Teck-Peng | en_US |
dc.date.accessioned | 2022-03-18T06:07:27Z | - |
dc.date.available | 2022-03-18T06:07:27Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Xie, P., Sun, Z., Li, S., Cai, X., Qiu, J., Fu, W., Gao, C., Wu, S., Yang, X. & Loh, T. (2020). Reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols. Organic Letters, 22(12), 4893-4897. https://dx.doi.org/10.1021/acs.orglett.0c01747 | en_US |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.uri | https://hdl.handle.net/10356/155331 | - |
dc.description.abstract | A reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols was developed. In this reaction, the hydrogen bond interaction between allylic alcohols and sulfinic acids allowed for reciprocal activation, which enabled a dehydrative cross-coupling process to occur under mild reaction conditions. This reaction worked in an environmentally friendly manner, yielding water as the only byproduct. A variety of allylic sulfones could be obtained in good to excellent yields with wide functional group tolerance. In gram scale reactions, allylic sulfones could be conveniently isolated in high yield by filtration. | en_US |
dc.description.sponsorship | Ministry of Education (MOE) | en_US |
dc.language.iso | en | en_US |
dc.relation | 2016-T1-002-043 | en_US |
dc.relation | RG111/16 | en_US |
dc.relation.ispartof | Organic Letters | en_US |
dc.rights | © 2020 American Chemical Society. All rights reserved. | en_US |
dc.subject | Science::Chemistry | en_US |
dc.title | Reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols | en_US |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en_US |
dc.identifier.doi | 10.1021/acs.orglett.0c01747 | - |
dc.identifier.pmid | 32496788 | - |
dc.identifier.scopus | 2-s2.0-85086584379 | - |
dc.identifier.issue | 12 | en_US |
dc.identifier.volume | 22 | en_US |
dc.identifier.spage | 4893 | en_US |
dc.identifier.epage | 4897 | en_US |
dc.subject.keywords | Reciprocal-Activation Strategy | en_US |
dc.subject.keywords | Allylic Sulfination | en_US |
dc.description.acknowledgement | The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (21702108), the Natural Science Foundation of Jiangsu Province, China (BK20160977), the Six Talent Peaks Project gsu Province (YY-033), Grant MOE2016-T1-002-043 (RG111/16) from the Ministry of Education of Singapore, and Nanjing Tech University (39837101). | en_US |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
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