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Title: Alkaline-earth metal catalyzed dehydrative allylic alkylation
Authors: Xie, Peizhong
Li, Shuangshuang
Liu, Yanan
Cai, Xinying
Wang, Jinyu
Yang, Xiaobo
Loh, Teck-Peng
Keywords: Science::Chemistry
Issue Date: 2020
Source: Xie, P., Li, S., Liu, Y., Cai, X., Wang, J., Yang, X. & Loh, T. (2020). Alkaline-earth metal catalyzed dehydrative allylic alkylation. Organic Letters, 22(1), 31-35.
Project: MOE2016-T1-002-043
Journal: Organic Letters
Abstract: An alkaline-earth metal catalytic system for environmentally benign allylic alkylation was developed. Allylic alcohols can be utilized directly at room temperature in this transition-metal-free process, producing water as the only byproduct. A variety of allylic compounds, including the ones containing all-carbonyl quaternary centers, can be obtained with high yields.
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.9b03730
Rights: © 2019 American Chemical Society. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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