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Title: Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts
Authors: Pal, Kumar Bhaskar
Lee, Jiande
Das, Mrinmoy
Liu, Xue-Wei
Keywords: Science::Chemistry
Issue Date: 2020
Source: Pal, K. B., Lee, J., Das, M. & Liu, X. (2020). Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts. Organic and Biomolecular Chemistry, 18(12), 2242-2251.
Project: RG120/18
MOE2013- T3-1-002 
Journal: Organic and Biomolecular Chemistry
Abstract: An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of glycals, including d-glucal, d-galactal, d-allal, l-rhamnal, l-fucal, l-arabinal, d-maltal, and d-lactal, occurred effectively and the corresponding C-glycosides were obtained in moderate to good yields. This protocol is commended as a significant addition to the field of carbohydrate chemistry due to the rich functional group compatibility, broad range of substrate scope and exceptional α-stereoselectivity.
ISSN: 1477-0520
DOI: 10.1039/d0ob00247j
Rights: © The Royal Society of Chemistry 2020. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:NEWRI Journal Articles
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