Please use this identifier to cite or link to this item:
|Title:||Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts||Authors:||Pal, Kumar Bhaskar
|Keywords:||Science::Chemistry||Issue Date:||2020||Source:||Pal, K. B., Lee, J., Das, M. & Liu, X. (2020). Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts. Organic and Biomolecular Chemistry, 18(12), 2242-2251. https://dx.doi.org/10.1039/d0ob00247j||Project:||RG120/18
|Journal:||Organic and Biomolecular Chemistry||Abstract:||An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of glycals, including d-glucal, d-galactal, d-allal, l-rhamnal, l-fucal, l-arabinal, d-maltal, and d-lactal, occurred effectively and the corresponding C-glycosides were obtained in moderate to good yields. This protocol is commended as a significant addition to the field of carbohydrate chemistry due to the rich functional group compatibility, broad range of substrate scope and exceptional α-stereoselectivity.||URI:||https://hdl.handle.net/10356/155454||ISSN:||1477-0520||DOI:||10.1039/d0ob00247j||Rights:||© The Royal Society of Chemistry 2020. All rights reserved.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||NEWRI Journal Articles|
SPMS Journal Articles
Updated on Jun 29, 2022
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.