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https://hdl.handle.net/10356/155454
Title: | Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts | Authors: | Pal, Kumar Bhaskar Lee, Jiande Das, Mrinmoy Liu, Xue-Wei |
Keywords: | Science::Chemistry | Issue Date: | 2020 | Source: | Pal, K. B., Lee, J., Das, M. & Liu, X. (2020). Palladium(ii)-catalyzed stereoselective synthesis of C-glycosides from glycals with diaryliodonium salts. Organic and Biomolecular Chemistry, 18(12), 2242-2251. https://dx.doi.org/10.1039/d0ob00247j | Project: | RG120/18 MOE2013- T3-1-002 NRF2016NRF-NSFC002-005 |
Journal: | Organic and Biomolecular Chemistry | Abstract: | An efficient palladium(ii) mediated C-glycosylation of glycals with diaryliodonium salts is described, providing a new strategy for the synthesis of 2,3-dideoxy C-aryl glycosides with excellent stereoselectivity. The C-glycosylation of a diverse range of glycals, including d-glucal, d-galactal, d-allal, l-rhamnal, l-fucal, l-arabinal, d-maltal, and d-lactal, occurred effectively and the corresponding C-glycosides were obtained in moderate to good yields. This protocol is commended as a significant addition to the field of carbohydrate chemistry due to the rich functional group compatibility, broad range of substrate scope and exceptional α-stereoselectivity. | URI: | https://hdl.handle.net/10356/155454 | ISSN: | 1477-0520 | DOI: | 10.1039/d0ob00247j | Schools: | School of Physical and Mathematical Sciences | Research Centres: | Nanyang Environment and Water Research Institute | Rights: | © The Royal Society of Chemistry 2020. All rights reserved. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | NEWRI Journal Articles SPMS Journal Articles |
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