Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/155587
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dc.contributor.authorSarkar, Jiten_US
dc.contributor.authorLim, Ying Fayeen_US
dc.contributor.authorGoto, Atushien_US
dc.date.accessioned2022-03-08T08:42:35Z-
dc.date.available2022-03-08T08:42:35Z-
dc.date.issued2021-
dc.identifier.citationSarkar, J., Lim, Y. F. & Goto, A. (2021). Synthesis of biologically decomposable terpolymer nanocapsules and higher-order nanoassemblies using RCMP-PISA. Macromolecular Chemistry and Physics, 222(24), 2100349-. https://dx.doi.org/10.1002/macp.202100349en_US
dc.identifier.issn1022-1352en_US
dc.identifier.urihttps://hdl.handle.net/10356/155587-
dc.description.abstractTerpolymers are used to generate bio-decomposable self-assemblies. PEG-PVL-PGMA terpolymers are synthesized via a combination of organocatalyzed living radical polymerization (RCMP) with polymerization-induced self-assembly (PISA), generating vesicle, multicompartment micelle (MCM), and core-compartmentalized worm (CCW), where PEG, PVL, and PGMA are poly(ethylene glycol) monomethyl ether, poly(δ-valerolactone), and poly(glycidyl methacrylate) and PGMA is grown during the PISA. MCM and CCW are uniquely obtainable using terpolymers. The PVL segment is biodegradable, and the obtained assemblies are bio-decomposable. Heavy metal-free and sulfur-free synthesis and bio-decomposability of the assemblies are attractive features.en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF-NRFI05-2019-0001en_US
dc.relation.ispartofMacromolecular Chemistry and Physicsen_US
dc.rightsThis is the peer reviewed version of the following article: Sarkar, J., Lim, Y. F. & Goto, A. (2021). Synthesis of biologically decomposable terpolymer nanocapsules and higher-order nanoassemblies using RCMP-PISA. Macromolecular Chemistry and Physics, 222(24), 2100349-, which has been published in final form at https://doi.org/10.1002/macp.202100349. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectScience::Chemistryen_US
dc.titleSynthesis of biologically decomposable terpolymer nanocapsules and higher-order nanoassemblies using RCMP-PISAen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1002/macp.202100349-
dc.description.versionAccepted versionen_US
dc.identifier.scopus2-s2.0-85119061788-
dc.identifier.issue24en_US
dc.identifier.volume222en_US
dc.identifier.spage2100349en_US
dc.subject.keywordsBio-Decomposabilityen_US
dc.subject.keywordsHigher-Order Assemblieen_US
dc.description.acknowledgementThis work was supported by the National Research Foundation (NRF) Investigatorship in Singapore (NRF-NRFI05-2019-0001).en_US
item.grantfulltextembargo_20230107-
item.fulltextWith Fulltext-
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