Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/156450
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dc.contributor.authorGuo, Shashaen_US
dc.contributor.authorFu, Jiecaien_US
dc.contributor.authorZhang, Peikunen_US
dc.contributor.authorZhu, Chaoen_US
dc.contributor.authorYao, Hemingen_US
dc.contributor.authorXu, Manzhangen_US
dc.contributor.authorAn, Boxingen_US
dc.contributor.authorWang, Xinglien_US
dc.contributor.authorTang, Bijunen_US
dc.contributor.authorDeng, Yaen_US
dc.contributor.authorSalim, Teddyen_US
dc.contributor.authorDu, Hongchuen_US
dc.contributor.authorDunin-Borkowski, Rafal E.en_US
dc.contributor.authorXu, Mingquanen_US
dc.contributor.authorZhou, Wuen_US
dc.contributor.authorTay, Beng Kangen_US
dc.contributor.authorZhu, Chaoen_US
dc.contributor.authorHe, Yanchaoen_US
dc.contributor.authorHofmann, Marioen_US
dc.contributor.authorHsieh, Ya-Pingen_US
dc.contributor.authorGuo, Wanlinen_US
dc.contributor.authorNg, Michaelen_US
dc.contributor.authorJia, Chunlinen_US
dc.contributor.authorZhang, Zhuhuaen_US
dc.contributor.authorHe, Yongminen_US
dc.contributor.authorLiu, Zhengen_US
dc.date.accessioned2022-04-20T06:21:05Z-
dc.date.available2022-04-20T06:21:05Z-
dc.date.issued2022-
dc.identifier.citationGuo, S., Fu, J., Zhang, P., Zhu, C., Yao, H., Xu, M., An, B., Wang, X., Tang, B., Deng, Y., Salim, T., Du, H., Dunin-Borkowski, R. E., Xu, M., Zhou, W., Tay, B. K., Zhu, C., He, Y., Hofmann, M., ...Liu, Z. (2022). Direct growth of single-metal-atom chains. Nature Synthesis, 1(3), 245-253. https://dx.doi.org/10.1038/s44160-022-00038-zen_US
dc.identifier.issn2731-0582en_US
dc.identifier.urihttps://hdl.handle.net/10356/156450-
dc.description.abstractSingle-metal-atom chains (SMACs), as the smallest one-dimensional structure, have intriguing physical and chemical properties. Although several SMACs have been realized so far, their controllable fabrication remains challenging due to the need to arrange single atoms in an atomically precise manner. Here we develop a chemical vapour co-deposition method to construct a wafer-scale network of platinum SMACs in atom-thin films. The obtained atomic chains possess an average length of up to ~17 nm and a high density of over 10 wt%. Interestingly, as a consequence of the electronic delocalization of platinum atoms along the chain, this atomically coherent one-dimensional channel delivers a metallic behaviour, as revealed by electronic measurements, first-principles calculations and complex network modelling. Our strategy is potentially extendable to other transition metals such as cobalt, enriching the toolbox for manufacturing SMACs and paving the way for the fundamental study of one-dimensional systems and the development of devices comprising monoatomic chains.en_US
dc.description.sponsorshipAgency for Science, Technology and Research (A*STAR)en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF-CRP22-2019-0007en_US
dc.relationNRF-CRP21-2018-0007en_US
dc.relationMOE2019-T2-2-105en_US
dc.relationA2083c0052en_US
dc.relationMOE2019 T1-001-113en_US
dc.relationRG4/17en_US
dc.relationRG7/18en_US
dc.relation.ispartofNature Synthesisen_US
dc.rights© 2022, The Author(s), under exclusive licence to Springer Nature Limited. All rights reserved. This paper was published in Nature Synthesis and is made available with permission of The Author(s).en_US
dc.subjectEngineering::Materials::Nanostructured materialsen_US
dc.subjectEngineering::Materials::Energy materialsen_US
dc.titleDirect growth of single-metal-atom chainsen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Electrical and Electronic Engineeringen_US
dc.contributor.researchCNRS International NTU THALES Research Alliancesen_US
dc.identifier.doi10.1038/s44160-022-00038-z-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.issue3en_US
dc.identifier.volume1en_US
dc.identifier.spage245en_US
dc.identifier.epage253en_US
dc.subject.keywordsSingle-Metal-Atom Chainsen_US
dc.subject.keywordsNanomaterialsen_US
dc.description.acknowledgementThis work was supported by the support from National Research Foundation Singapore programme NRF-CRP22-2019-0007 and NRF-CRP21-2018-0007. This work is also supported by the Ministry of Education, Singapore, under its AcRF Tier 2 (MOE2019-T2-2-105) and AcRF Tier 1 RG4/17 and RG7/18. This research is also supported by A*STAR under its AME IRG Grant (Project No. A2083c0052). The work at NUAA was supported by the National Key Research and Development Program of China (2019YFA0705400), National Natural Science Foundation of China (11772153, 22073048), the Natural Science Foundation of Jiangsu Province (BK20190018), and a Project by the Priority Academic Program Development of Jiangsu Higher Education Institutions. W.Z. acknowledges the support of the Beijing Outstanding Young Scientist Program (BJJWZYJH01201914430039). B.T. and X.W. acknowledge the support from the Ministry of Education, Singapore (MOE2019 T1-001-113). H.Y. and M. N. acknowledge the support from the Hong Kong Research Grant Council, Hong Kong (HKRGC GRF 12300218, 12300519, 17201020, 17300021, and UGC-RMGS 207300829). H.D. acknowledges the support from German Research Foundation (DFG) under the Grant SFB917 Nanoswitches.en_US
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