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https://hdl.handle.net/10356/156747
Title: | Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process | Authors: | Aydogan, Canus Aykac, F. Simal Yilmaz, Gorkem Chew, Ye Qiu Goto, Atushi Yagci, Yusuf |
Keywords: | Science::Chemistry::Organic chemistry::Polymers | Issue Date: | 2022 | Source: | Aydogan, C., Aykac, F. S., Yilmaz, G., Chew, Y. Q., Goto, A. & Yagci, Y. (2022). Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process. ACS Macro Letters, 11(3), 342-346. https://dx.doi.org/10.1021/acsmacrolett.2c00004 | Project: | NRF-NRFI05-2019-0001 | Journal: | ACS Macro Letters | Abstract: | A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations. | URI: | https://hdl.handle.net/10356/156747 | ISSN: | 2161-1653 | DOI: | 10.1021/acsmacrolett.2c00004 | Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Macro Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsmacrolett.2c00004. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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Accepted version.pdf | 835.51 kB | Adobe PDF | View/Open |
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