Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/156747
Title: Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process
Authors: Aydogan, Canus
Aykac, F. Simal
Yilmaz, Gorkem
Chew, Ye Qiu
Goto, Atushi
Yagci, Yusuf
Keywords: Science::Chemistry::Organic chemistry::Polymers
Issue Date: 2022
Source: Aydogan, C., Aykac, F. S., Yilmaz, G., Chew, Y. Q., Goto, A. & Yagci, Y. (2022). Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process. ACS Macro Letters, 11(3), 342-346. https://dx.doi.org/10.1021/acsmacrolett.2c00004
Project: NRF-NRFI05-2019-0001
Journal: ACS Macro Letters
Abstract: A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.
URI: https://hdl.handle.net/10356/156747
ISSN: 2161-1653
DOI: 10.1021/acsmacrolett.2c00004
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Macro Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsmacrolett.2c00004.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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