Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/156747
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dc.contributor.authorAydogan, Canusen_US
dc.contributor.authorAykac, F. Simalen_US
dc.contributor.authorYilmaz, Gorkemen_US
dc.contributor.authorChew, Ye Qiuen_US
dc.contributor.authorGoto, Atsushien_US
dc.contributor.authorYagci, Yusufen_US
dc.date.accessioned2022-04-21T04:31:05Z-
dc.date.available2022-04-21T04:31:05Z-
dc.date.issued2022-
dc.identifier.citationAydogan, C., Aykac, F. S., Yilmaz, G., Chew, Y. Q., Goto, A. & Yagci, Y. (2022). Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process. ACS Macro Letters, 11(3), 342-346. https://dx.doi.org/10.1021/acsmacrolett.2c00004en_US
dc.identifier.issn2161-1653en_US
dc.identifier.urihttps://hdl.handle.net/10356/156747-
dc.description.abstractA versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF-NRFI05-2019-0001en_US
dc.relation.ispartofACS Macro Lettersen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Macro Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsmacrolett.2c00004.en_US
dc.subjectScience::Chemistry::Organic chemistry::Polymersen_US
dc.titleSynthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation processen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acsmacrolett.2c00004-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.scopus2-s2.0-85125922391-
dc.identifier.issue3en_US
dc.identifier.volume11en_US
dc.identifier.spage342en_US
dc.identifier.epage346en_US
dc.subject.keywordsCopolymerizationen_US
dc.subject.keywordsPolymersen_US
dc.description.acknowledgementThe authors acknowledge the financial support from The Scientific and Technological Research Council of Turkey (Project 120C121) and the Istanbul Technical University Research Fund and National Research Foundation (NRF) Investigatorship in Singapore (NRF-NRFI05-2019-0001).en_US
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