Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/156807
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dc.contributor.authorWang, Houen_US
dc.contributor.authorYang, Yien_US
dc.contributor.authorYuan, Xingzhongen_US
dc.contributor.authorTeo, Wei Liangen_US
dc.contributor.authorWu, Yanen_US
dc.contributor.authorTang, Linen_US
dc.contributor.authorZhao, Yanlien_US
dc.date.accessioned2022-04-25T07:19:18Z-
dc.date.available2022-04-25T07:19:18Z-
dc.date.issued2022-
dc.identifier.citationWang, H., Yang, Y., Yuan, X., Teo, W. L., Wu, Y., Tang, L. & Zhao, Y. (2022). Structure−performance correlation guided applications of covalent organic frameworks. Materials Today. https://dx.doi.org/10.1016/j.mattod.2022.02.001en_US
dc.identifier.issn1369-7021en_US
dc.identifier.urihttps://hdl.handle.net/10356/156807-
dc.description.abstractPre-designed structures and tailor-made functions make covalent organic frameworks (COFs) quickly become promising reticular platforms for multidisciplinary fields. Despite the overarching success, controllable and large-scale synthesis of COFs is still a huge challenge. Moreover, the relationship between the structure and performance of COFs in various fields has not been well understood, seriously limiting their practical applications. In this review, we provide an insightful and fundamental understanding of COFs from structural perspectives, and correlate them with eventual performance in practical applications. By summarizing both the top-down and bottom-up approaches, we address how typical issues, such as the size, morphology, dispersity and stability of COFs, are resolved, which should be crucial for their function-oriented and large-scale production. Structural and physicochemical properties, such as pores, ligands, stacking, linkages, functional group, morphology, crystallinity, dimensionality and wetting, are also discussed in relation to various functions. In addition, in-depth discussions regarding the correlations between structural characteristics of COFs and their performance in catalysis, energy storage, gas/liquid adsorption and membrane separation are presented. Finally, perspectives for the future direction of this field are proposed, to provide useful guidance for the function-oriented design and scalable production of COFs to meet the practical requirements of applications.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.language.isoenen_US
dc.relationMOET2EP10120-0003en_US
dc.relationRG3/21en_US
dc.relation.ispartofMaterials Todayen_US
dc.rights© 2022 Elsevier Ltd. All rights reserved. This paper was published in Materials Today and is made available with permission of Elsevier Ltd.en_US
dc.subjectScience::Chemistryen_US
dc.titleStructure−performance correlation guided applications of covalent organic frameworksen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1016/j.mattod.2022.02.001-
dc.description.versionSubmitted/Accepted versionen_US
dc.subject.keywordsCovalent Organic Frameworksen_US
dc.subject.keywordsLarge-Scale Synthesisen_US
dc.description.acknowledgementThe authors gratefully acknowledge the financial support provided by the Projects of the National Nature Science Foundation of China (No. 22178091, 72088101 and 51739004). This research was also supported by the Ministry of Education Singapore under the Academic Research Funds (No. MOET2EP10120-0003 and RG3/21).en_US
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