Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/156936
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dc.contributor.authorZeng, Yinxiangen_US
dc.contributor.authorWang, Yanen_US
dc.contributor.authorJin, Qien_US
dc.contributor.authorPei, Zhihaoen_US
dc.contributor.authorLuan, Deyanen_US
dc.contributor.authorZhang, Xitianen_US
dc.contributor.authorLou, David Xiong Wenen_US
dc.date.accessioned2022-04-27T07:28:27Z-
dc.date.available2022-04-27T07:28:27Z-
dc.date.issued2021-
dc.identifier.citationZeng, Y., Wang, Y., Jin, Q., Pei, Z., Luan, D., Zhang, X. & Lou, D. X. W. (2021). Rationally designed Mn₂O₃ -ZnMn₂ O₄ hollow heterostructures from metal-organic frameworks for stable Zn-ion storage. Angewandte Chemie International Edition, 60(49), 25793-25798. https://dx.doi.org/10.1002/anie.202113487en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttps://hdl.handle.net/10356/156936-
dc.description.abstractMn-based oxides have sparked extensive scientific interest for aqueous Zn-ion batteries due to the rich abundance, plentiful oxidation states, and high output voltage. However, the further development of Mn-based oxides is severely hindered by the rapid capacity decay during cycling. Herein, a two-step metal-organic framework (MOF)-engaged templating strategy has been developed to rationally synthesize heterostructured Mn2 O3 -ZnMn2 O4 hollow octahedrons (MO-ZMO HOs) for stable zinc ion storage. The distinctive composition and hollow heterostructure endow MO-ZMO HOs with abundant active sites, enhanced electric conductivity, and superior structural stability. By virtue of these advantages, the MO-ZMO HOs electrode shows high reversible capacity, impressive rate performance, and outstanding electrochemical stability. Furthermore, ex situ characterizations reveal that the charge storage of MO-ZMO HOs mainly originates from the highly reversible Zn2+ insertion/extraction reactions.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.language.isoenen_US
dc.relationRG3/20en_US
dc.relationMOE2017-T2-2–003en_US
dc.relation.ispartofAngewandte Chemie International Editionen_US
dc.rightsThis is the peer reviewed version of the following article: Zeng, Y., Wang, Y., Jin, Q., Pei, Z., Luan, D., Zhang, X. & Lou, D. X. W. (2021). Rationally designed Mn₂O₃ -ZnMn₂ O₄ hollow heterostructures from metal-organic frameworks for stable Zn-ion storage. Angewandte Chemie International Edition, 60(49), 25793-25798, which has been published in final form at https://doi.org/10.1002/anie.202113487. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectEngineering::Chemical engineeringen_US
dc.titleRationally designed Mn₂O₃ -ZnMn₂ O₄ hollow heterostructures from metal-organic frameworks for stable Zn-ion storageen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.identifier.doi10.1002/anie.202113487-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.pmid34676649-
dc.identifier.scopus2-s2.0-85118509500-
dc.identifier.issue49en_US
dc.identifier.volume60en_US
dc.identifier.spage25793en_US
dc.identifier.epage25798en_US
dc.subject.keywordsHeterostructuresen_US
dc.subject.keywordsHollow Octahedronsen_US
dc.description.acknowledgementX.W.L. acknowledges the funding support from the Ministry of Education of Singapore through the Academic Research Fund (AcRF)Tier-1 grant (RG3/20) and Tier-2 grant (MOE2017-T2-2–003).en_US
item.fulltextWith Fulltext-
item.grantfulltextembargo_20221208-
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