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|Title:||Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles||Authors:||Seah, Jeffrey Wee Kiong
Pullarkat, Sumod A.
|Keywords:||Science::Chemistry||Issue Date:||2021||Source:||Seah, J. W. K., Li, Y., Pullarkat, S. A. & Leung, P. (2021). Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles. Organometallics, 40(13), 2118-2122. https://dx.doi.org/10.1021/acs.organomet.1c00262||Project:||2019- T1-001-094||Journal:||Organometallics||Abstract:||Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral phosphine-NHC palladium(II) complex with excellent overall conversion.||URI:||https://hdl.handle.net/10356/157004||ISSN:||0276-7333||DOI:||10.1021/acs.organomet.1c00262||Rights:||This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.1c00262.||Fulltext Permission:||embargo_20220719||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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Updated on May 14, 2022
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