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https://hdl.handle.net/10356/157592| Title: | Reversible CO₂ activation by a N-phosphinoamidinato digermyne | Authors: | Fan, Jun Quek, Shina Yang, Ming-Chung Zhang, Zheng-Feng Su, Ming-Der So, Cheuk-Wai |
Keywords: | Science::Chemistry | Issue Date: | 2022 | Source: | Fan, J., Quek, S., Yang, M., Zhang, Z., Su, M. & So, C. (2022). Reversible CO₂ activation by a N-phosphinoamidinato digermyne. Chemical Communications, 58(7), 1033-1036. https://dx.doi.org/10.1039/D1CC05391D | Project: | NRF2018-NRF-ANR026 Si-POP MOE2019-T2-2-129 |
Journal: | Chemical Communications | Abstract: | The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph)=C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively. | URI: | https://hdl.handle.net/10356/157592 | ISSN: | 1359-7345 | DOI: | 10.1039/D1CC05391D | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2022 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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|---|---|---|---|---|
| manuscript_GeGeCO2_CWSo_revised_DrNTU.pdf | 969.71 kB | Adobe PDF |  View/Open |
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