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Title: Reversible CO₂ activation by a N-phosphinoamidinato digermyne
Authors: Fan, Jun
Quek, Shina
Yang, Ming-Chung
Zhang, Zheng-Feng
Su, Ming-Der
So, Cheuk-Wai
Keywords: Science::Chemistry
Issue Date: 2022
Source: Fan, J., Quek, S., Yang, M., Zhang, Z., Su, M. & So, C. (2022). Reversible CO₂ activation by a N-phosphinoamidinato digermyne. Chemical Communications, 58(7), 1033-1036.
Project: NRF2018-NRF-ANR026 Si-POP
Journal: Chemical Communications 
Abstract: The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph)=C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively.
ISSN: 1359-7345
DOI: 10.1039/D1CC05391D
Rights: © 2022 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry.
Fulltext Permission: embargo_20221225
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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