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https://hdl.handle.net/10356/157593| Title: | Amidinatoamidosilylene−Dibromodiborene | Authors: | Fan, Jun Yang, Ming-Chung Su, Ming-Der So, Cheuk-Wai |
Keywords: | Science::Chemistry | Issue Date: | 2021 | Source: | Fan, J., Yang, M., Su, M. & So, C. (2021). Amidinatoamidosilylene−Dibromodiborene. Inorganic Chemistry, 60(21), 16065-16069. https://dx.doi.org/10.1021/acs.inorgchem.1c02541 | Project: | NRF2018-NRF-ANR026 Si-POP MOE2019-T2-2-129 |
Journal: | Inorganic Chemistry | Abstract: | The amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3). | URI: | https://hdl.handle.net/10356/157593 | ISSN: | 0020-1669 | DOI: | 10.1021/acs.inorgchem.1c02541 | Schools: | School of Physical and Mathematical Sciences | Rights: | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.1c02541. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| manuscript_Sidiborene_revised.pdf | 826.51 kB | Adobe PDF |  View/Open |
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