Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/157593
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dc.contributor.authorFan, Junen_US
dc.contributor.authorYang, Ming-Chungen_US
dc.contributor.authorSu, Ming-Deren_US
dc.contributor.authorSo, Cheuk-Waien_US
dc.date.accessioned2022-05-15T07:29:14Z-
dc.date.available2022-05-15T07:29:14Z-
dc.date.issued2021-
dc.identifier.citationFan, J., Yang, M., Su, M. & So, C. (2021). Amidinatoamidosilylene−Dibromodiborene. Inorganic Chemistry, 60(21), 16065-16069. https://dx.doi.org/10.1021/acs.inorgchem.1c02541en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttps://hdl.handle.net/10356/157593-
dc.description.abstractThe amidinato amidosilylene [LSiNMe2] (1, L = PhC(NtBu)2) was reacted with B2Br4(SMe2)2 in toluene at room temperature to form the bis(silylene)-tetrabromodiborane [L{Me2N}Si]2B2Br4 (2). It was then reacted with excess KC8 in THF at room temperature to afford the bis(silylene)-dibromodiborene [L{Me2N}Si]2B2Br2 (3).en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF2018-NRF-ANR026 Si-POPen_US
dc.relationMOE2019-T2-2-129en_US
dc.relation.ispartofInorganic Chemistryen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.1c02541.en_US
dc.subjectScience::Chemistryen_US
dc.titleAmidinatoamidosilylene−Dibromodiboreneen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.inorgchem.1c02541-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.issue21en_US
dc.identifier.volume60en_US
dc.identifier.spage16065en_US
dc.identifier.epage16069en_US
dc.subject.keywordsSiliconen_US
dc.subject.keywordsBromine Compoundsen_US
dc.description.acknowledgementC.-W.S. thanks the National Research Foundation Singapore, NRF-ANR (NRF2018-NRF-ANR026 Si-POP), and Ministry of Education Singapore, AcRF Tier 2 (MOE2019-T2-2-129), for financial support. M.-C.Y. and M.-D.S. acknowledge the National Center for High-Performance Computing of Taiwan for generous amounts of computing time and the Ministry of Science and Technology of Taiwan for financial support.en_US
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