Please use this identifier to cite or link to this item:
Title: Photoinitiated stereoselective direct C(sp²)–H perfluoroalkylation and difluoroacetylation of enamides
Authors: Zhao, Kai
Guo, Jing-Yu
Guan, Ting
Wang, Ying-Xue
Tao, Ji-Yu
Zhang, Yu
Zhang, Qing-Hong
Ni, Kun
Loh, Teck-Peng
Keywords: Science::Chemistry
Issue Date: 2021
Source: Zhao, K., Guo, J., Guan, T., Wang, Y., Tao, J., Zhang, Y., Zhang, Q., Ni, K. & Loh, T. (2021). Photoinitiated stereoselective direct C(sp²)–H perfluoroalkylation and difluoroacetylation of enamides. Organic Chemistry Frontiers, 8(15), 4086-4094.
Journal: Organic Chemistry Frontiers
Abstract: A photoinitiated perfluoroalkylative coupling of enamides with perfluoroalkyl iodides and a visible-light-induced difluoroacetylation of enamides with ethyl bromodifluoroacetate have been developed, respectively. These transformations allow the efficacious and straightforward incorporation of biologically and physiologically privileged fluoro-containing moieties into synthetically eminent enamide scaffolds with excellent regio- and stereoselectivities under mild and environmentally friendly conditions.
ISSN: 2052-4129
DOI: 10.1039/D1QO00605C
Schools: School of Physical and Mathematical Sciences 
Rights: © 2021 the Partner Organisations. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

Citations 20

Updated on Sep 26, 2023

Web of ScienceTM
Citations 10

Updated on Sep 21, 2023

Page view(s)

Updated on Sep 26, 2023

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.