Please use this identifier to cite or link to this item:
Title: Visible-light-induced trifluoromethylation of allylic alcohols
Authors: Li, Bowen
Zeng, Wubing
Wang, Lin
Geng, Zhishuai
Loh, Teck-Peng
Xie, Peizhong
Keywords: Science::Chemistry
Issue Date: 2021
Source: Li, B., Zeng, W., Wang, L., Geng, Z., Loh, T. & Xie, P. (2021). Visible-light-induced trifluoromethylation of allylic alcohols. Organic Letters, 23(13), 5235-5240.
Journal: Organic Letters
Abstract: An organic photoredox-catalyzed dehydroxylative trifluoromethylation of allylic alcohols was developed in an environmentally benign manner. In this reaction, the readily available CF3SO2Na was selected as the trifluoromethylation reagent. The in situ generated byproduct SO2 was reutilized to activate C-OH bond, which enabled this dehydroxylative trifluoromethylation to be performed conveniently. A variety of multifunctionalized CF3-allylic compounds were obtained in high yields and excellent stereoselectivity.
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.1c01767
Schools: School of Physical and Mathematical Sciences 
Rights: © 2021 American Chemical Society. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

Citations 20

Updated on Sep 23, 2023

Web of ScienceTM
Citations 20

Updated on Sep 28, 2023

Page view(s)

Updated on Sep 30, 2023

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.