Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/161105
Full metadata record
DC FieldValueLanguage
dc.contributor.authorBarát, Viktoren_US
dc.contributor.authorBudanovic, Majaen_US
dc.contributor.authorTam, Si Manen_US
dc.contributor.authorHuh, Juneen_US
dc.contributor.authorWebster, Richard Daviden_US
dc.contributor.authorStuparu, Mihaiela Corinaen_US
dc.date.accessioned2022-08-16T01:28:10Z-
dc.date.available2022-08-16T01:28:10Z-
dc.date.issued2020-
dc.identifier.citationBarát, V., Budanovic, M., Tam, S. M., Huh, J., Webster, R. D. & Stuparu, M. C. (2020). Corannulene-based electron acceptors: combining modular and practical synthesis with electron affinity and solubility. Chemistry - A European Journal, 26(15), 3231-3235. https://dx.doi.org/10.1002/chem.201905521en_US
dc.identifier.issn0947-6539en_US
dc.identifier.urihttps://hdl.handle.net/10356/161105-
dc.description.abstractIt is shown in this work that high electron affinity can be combined with high solubility and practical accessibility in corannulene-based electron acceptors. The electron affinity originates from the presence of three different types of electron-withdrawing groups (imide, sulfone, and trifluoromethyl) on the aromatic scaffold. The imide substituent further hosts a long alkyl chain (C18 H37 ) to boast solubility in a wide range of organic solvents. The synthesis is modular and consists of three simple steps from a commonly available corannulene derivative with an overall isolated yield of 22-27 %.en_US
dc.description.sponsorshipAgency for Science, Technology and Research (A*STAR)en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relationMOE2017-T1-001-17en_US
dc.relationM4011792en_US
dc.relation2018-T1-001-176en_US
dc.relationM4012047en_US
dc.relationA1883c0006en_US
dc.relationM4081566en_US
dc.relation.ispartofChemistry - A European Journalen_US
dc.rights© 2020 Wiley-VCHVerlag GmbH & Co. KGaA, Weinheim. All rights reserved.en_US
dc.subjectScience::Chemistryen_US
dc.subjectEngineering::Materialsen_US
dc.titleCorannulene-based electron acceptors: combining modular and practical synthesis with electron affinity and solubilityen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1002/chem.201905521-
dc.identifier.pmid31975463-
dc.identifier.scopus2-s2.0-85079847637-
dc.identifier.issue15en_US
dc.identifier.volume26en_US
dc.identifier.spage3231en_US
dc.identifier.epage3235en_US
dc.subject.keywordsCorannuleneen_US
dc.subject.keywordsElectron-Deficient Compoundsen_US
dc.description.acknowledgementFinancial support from the Ministry of Education Singapore under the AcRF Tier 1 (MOE2017-T1-001-17, M4011792) (2018-T1-001-176, M4012047); Agency for Science, Technology and Research (A*STAR)-AME IRG A1883c0006; and NTU (M4081566) is gratefully acknowledged.en_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
Appears in Collections:MSE Journal Articles
SPMS Journal Articles

SCOPUSTM   
Citations 20

10
Updated on Jul 14, 2024

Web of ScienceTM
Citations 20

8
Updated on Oct 28, 2023

Page view(s)

188
Updated on Jul 20, 2024

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.