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Title: Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines
Authors: Barik, Chandan Kr
Ganguly, Rakesh
Li, Yongxin
Samanta, Samya
Leong, Weng Kee
Keywords: Science::Chemistry
Issue Date: 2021
Source: Barik, C. K., Ganguly, R., Li, Y., Samanta, S. & Leong, W. K. (2021). Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines. Journal of Cluster Science, 32(4), 929-935.
Project: RG15/17
Journal: Journal of Cluster Science
Abstract: The dianionic cluster [Os10(µ6-C)(CO)24]2− reacts with excess SbX3 or p-tolylSbX2 to form the monoanionic clusters [Os10{µ4-Sb(p-tolyl)nX2-n}(µ6-C)(CO)24]− (n = 0; X = Cl, I; n = 1, X = Cl) via insertion into an Os–Os bond. Further insertion into an Os–Os bond occurs when they are reacted further with excess iodine. The chemistry and structure of these clusters can be understood in terms of the isolobal analogy between [Sb(p-tolyl)nX2-n)]+ and I+.
ISSN: 1040-7278
DOI: 10.1007/s10876-020-01857-w
Schools: School of Physical and Mathematical Sciences 
Rights: © 2020 Springer Science+Business Media, LLC, part of Springer Nature. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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