Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/161180
Title: A neutral and aromatic boron-rich inorganic benzene
Authors: Ota, Kei
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2020
Source: Ota, K. & Kinjo, R. (2020). A neutral and aromatic boron-rich inorganic benzene. Angewandte Chemie International Edition, 59(16), 6572-6575. https://dx.doi.org/10.1002/anie.201915790
Project: MOE2018-T2-2-048(S) 
Journal: Angewandte Chemie International Edition 
Abstract: A neutral 1,4-diaza-2,3,5,6-tetraborinine derivative (3) featuring a 6π ring system has been synthesized and structurally characterized. The prospective aromatic nature of 3 was assessed by single-crystal X-ray analysis, NMR, and UV/Vis absorption spectroscopy as well as computational studies. Furthermore, preliminary reactivity investigations showed that 3 does not only react with diphenyl acetylene but also readily captures CO2 in a [4+2] cycloaddition under ambient conditions.
URI: https://hdl.handle.net/10356/161180
ISSN: 1433-7851
DOI: 10.1002/anie.201915790
Schools: School of Physical and Mathematical Sciences 
Rights: This is the peer reviewed version of the following article: Ota, K. & Kinjo, R. (2020). A neutral and aromatic boron-rich inorganic benzene. Angewandte Chemie International Edition, 59(16), 6572-6575, which has been published in final form at https://doi.org/10.1002/anie.201915790. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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