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Title: Heavier element-containing aromatics of [4n+2]-electron systems
Authors: Ota, Kei
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2021
Source: Ota, K. & Kinjo, R. (2021). Heavier element-containing aromatics of [4n+2]-electron systems. Chemical Society Reviews, 50(18), 10594-10673.
Project: MOE2018-T2-2- 048(S)
Journal: Chemical Society Reviews
Abstract: While the implication of the aromaticity concept has been dramatically expanded to date since its emergence in 1865, the classical [4n+2]/4n-electron counting protocol still plays an essential role in evaluating the aromatic nature of compounds. Over the last few decades, a variety of heavier heterocycles featuring the formal [4n+2] π-electron arrangements have been developed, which allows for assessing their aromatic nature. In this review, we present recent developments of the [4n+2]-electron systems of heavier heterocycles involving group 13-15 elements. The synthesis, spectroscopic data, structural parameters, computational data, and reactivity are introduced.
ISSN: 0306-0012
DOI: 10.1039/d0cs01354d
Schools: School of Physical and Mathematical Sciences 
Rights: © 2021 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Society Reviews and is made available with permission of The Royal Society of Chemistry.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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