Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/161184
Title: | Inorganic benzene valence isomers | Authors: | Ota, Kei Kinjo, Rei |
Keywords: | Science::Chemistry | Issue Date: | 2020 | Source: | Ota, K. & Kinjo, R. (2020). Inorganic benzene valence isomers. Chemistry - An Asian Journal, 15(17), 2558-2574. https://dx.doi.org/10.1002/asia.202000535 | Project: | MOE2018-T2-2-048(S) | Journal: | Chemistry - An Asian Journal | Abstract: | It has been computationally proposed that there are more than 200 possible isomeric structures for the C6H6 molecule, among which benzene (CH)6 represents the most thermodynamically stable molecule and its chemistry has been extensively developed. Three benzene valence isomers (CR)6, namely, prismane, Dewar benzene, and benzvalene, have also been synthesized to date. Incorporation of heteroatoms in the skeletal frameworks allows access to inorganic analogues of benzene and its valence isomers, which have attracted considerable attention due to their peculiar structural and electronic features. Experimentally, more than 30 examples of inorganic benzene and its valence isomers have been developed and characterized so far. In this contribution, their synthesis and characterization, as well as their stability and chemical properties, are discussed. | URI: | https://hdl.handle.net/10356/161184 | ISSN: | 1861-4728 | DOI: | 10.1002/asia.202000535 | Schools: | School of Physical and Mathematical Sciences | Rights: | This is the peer reviewed version of the following article: Ota, K. & Kinjo, R. (2020). Inorganic benzene valence isomers. Chemistry - An Asian Journal, 15(17), 2558-2574, which has been published in final form at https://doi.org/10.1002/asia.202000535. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Inorganic benzene valence isomers.pdf | 2.08 MB | Adobe PDF | View/Open |
SCOPUSTM
Citations
20
19
Updated on Mar 26, 2024
Web of ScienceTM
Citations
20
16
Updated on Oct 26, 2023
Page view(s)
92
Updated on Mar 29, 2024
Download(s) 50
126
Updated on Mar 29, 2024
Google ScholarTM
Check
Altmetric
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.