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Title: Crystalline boragermenes
Authors: Rao, Bin
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2020
Source: Rao, B. & Kinjo, R. (2020). Crystalline boragermenes. Angewandte Chemie International Edition, 59(8), 3147-3150.
Project: MOE2018-T2-2-048 (S)
Journal: Angewandte Chemie International Edition
Abstract: Boragermene 3 featuring a double bond between the Ge and dicoordinate B atoms has been synthesized for the first time by reacting the cyclic (alkyl)(boryl)germylene-PMe3 adduct 1 with Cl2 BN(SiMe3 )2 followed by reductive dehalogenation with KC8 . Addition of a Lewis base (Me NHC) to 3 leads to the formation of the corresponding adduct 4, which shows double bond character between the Ge and tricoordinate B atoms. Compound 3 undergoes hydrogenation with H2 concomitant with a complete scission of the Ge=B bond.
ISSN: 1433-7851
DOI: 10.1002/anie.201914644
Schools: School of Physical and Mathematical Sciences 
Rights: This is the peer reviewed version of the following article: Rao, B. & Kinjo, R. (2020). Crystalline boragermenes. Angewandte Chemie International Edition, 59(8), 3147-3150, which has been published in final form at This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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