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Title: Metal-catalyzed transformations of cyclopropanols via homoenolates
Authors: Sekiguchi, Yoshiya
Yoshikai, Naohiko
Keywords: Science::Chemistry
Issue Date: 2021
Source: Sekiguchi, Y. & Yoshikai, N. (2021). Metal-catalyzed transformations of cyclopropanols via homoenolates. Bulletin of the Chemical Society of Japan, 94(1), 265-280.
Project: MOE2016-T2-2-043
Journal: Bulletin of the Chemical Society of Japan
Abstract: Metal homoenolates represent uniquely useful organometallic intermediates in synthetic chemistry, allowing umpolung synthesis of β-functionalized carbonyl compounds. While siloxycyclopropanes had been established as reliable precursors to homoenolates, often stoichiometric, for diverse carboncarbon bond forming reactions, unprotected cyclopropanols have emerged as alternative and attractive precursors to homoenolates, often catalytically generated, in carboncarbon and carbonheteroatom bond-forming reactions. This review article provides an overview of the development of such homoenolate transformations, as classified with respect to the metals involved in the cyclopropane ring opening.
ISSN: 0009-2673
DOI: 10.1246/BCSJ.20200270
Schools: School of Physical and Mathematical Sciences 
Rights: © 2021 The Chemical Society of Japan. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
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