Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/161294
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dc.contributor.authorIto, Shingoen_US
dc.date.accessioned2022-08-24T03:04:28Z-
dc.date.available2022-08-24T03:04:28Z-
dc.date.issued2019-
dc.identifier.citationIto, S. (2019). The rapid synthesis of π-extended azacorannulenes. Journal of Synthetic Organic Chemistry, 77(11), 1128-1135. https://dx.doi.org/10.5059/yukigoseikyokaishi.77.1128en_US
dc.identifier.issn0037-9980en_US
dc.identifier.urihttps://hdl.handle.net/10356/161294-
dc.description.abstractIn this account we describe our recent development of rapid syntheses of π-extended azacorannulenes. The key to successful synthesis is the use of polycyclic aromatic azomethine ylides, which exhibit extremely high reactivity in sequential 1,3-dipolar cycloadditions with alkenes and alkynes followed by oxidation to form fused pyrroles. This efficient construction of the polycyclic pyrrole structure has led to the rapid synthesis of various π-extended azacorannulenes, which are characterized by their extended π-surface and highly curved, bowl-shaped structures. The present study provides useful insights toward the bottom-up synthesis and property elucidation of heteroatom-containing fullerenes and their fragment molecules.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.language.isoenen_US
dc.relation2018─ T1─ 002─ 021en_US
dc.relation.ispartofJournal of Synthetic Organic Chemistryen_US
dc.rights© 2019 The Society of Synthetic Organic Chemistry, Japan. All rights reserved.en_US
dc.subjectScience::Chemistryen_US
dc.titleThe rapid synthesis of π-extended azacorannulenesen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.5059/yukigoseikyokaishi.77.1128-
dc.identifier.scopus2-s2.0-85084929407-
dc.identifier.issue11en_US
dc.identifier.volume77en_US
dc.identifier.spage1128en_US
dc.identifier.epage1135en_US
dc.description.acknowledgementThis work was supported by JSPS KAKENHI, including Grant─ in─ Aids for Young Scientists (A) (No. 16H06030) and Challenging Exploratory Research (No. 24655096), and Nanyang Technological University and the Singapore Ministry of Education via Academic Research Fund Tier 1: 2018─ T1─ 002─ 021. The nancial support of the Yazaki Memorial Foundation for Science and Technology is greatly appreciated.en_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
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