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Title: The rapid synthesis of π-extended azacorannulenes
Authors: Ito, Shingo
Keywords: Science::Chemistry
Issue Date: 2019
Source: Ito, S. (2019). The rapid synthesis of π-extended azacorannulenes. Journal of Synthetic Organic Chemistry, 77(11), 1128-1135.
Project: 2018─ T1─ 002─ 021
Journal: Journal of Synthetic Organic Chemistry
Abstract: In this account we describe our recent development of rapid syntheses of π-extended azacorannulenes. The key to successful synthesis is the use of polycyclic aromatic azomethine ylides, which exhibit extremely high reactivity in sequential 1,3-dipolar cycloadditions with alkenes and alkynes followed by oxidation to form fused pyrroles. This efficient construction of the polycyclic pyrrole structure has led to the rapid synthesis of various π-extended azacorannulenes, which are characterized by their extended π-surface and highly curved, bowl-shaped structures. The present study provides useful insights toward the bottom-up synthesis and property elucidation of heteroatom-containing fullerenes and their fragment molecules.
ISSN: 0037-9980
DOI: 10.5059/yukigoseikyokaishi.77.1128
Schools: School of Physical and Mathematical Sciences 
Rights: © 2019 The Society of Synthetic Organic Chemistry, Japan. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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